Enhanced Fischer-Tropsch activity in ammonium nitrate pretreated cobalt-silica catalyst
نویسندگان
چکیده
منابع مشابه
The optimally performing Fischer-Tropsch catalyst.
Microkinetics simulations are presented based on DFT-determined elementary reaction steps of the Fischer-Tropsch (FT) reaction. The formation of long-chain hydrocarbons occurs on stepped Ru surfaces with CH as the inserting monomer, whereas planar Ru only produces methane because of slow CO activation. By varying the metal-carbon and metal-oxygen interaction energy, three reactivity regimes are...
متن کاملKCl Promoted Cobalt-iron Nanocatalysts Supported on Silica: Catalytic Performance and Characterization in Fischer-Tropsch Synthesis
The SiO2 supported cobalt-iron nano catalysts were prepared by the sol-gel method. This research investigated the effects of (Co/Fe) wt.%, different Co/Fe ratio at different temperature and loading of KCl wt.% for Fisher-Tropsch synthesis (FTS). The results were showed that the catalyst containing 50 wt.% (Co/Fe)/SiO2 (Co/Fe ratio is 70/30) which promoted with 0.6 wt.% KCl is an optimal nano ca...
متن کاملReactions of Olefins Added during Fischer-Tropsch Synthesis over Supported Cobalt Catalyst
The control on product distributions in Fischer-Tropsch synthesis by feeding olefins in the n-paraffin solvent over a 20 wt.% Co/SiO2 catalyst under the typical reaction conditions of 503K, 2.1MPa, H2/CO = 2, and co-fed olefins 16 mol% in CO base in a trickle bed reactor has been studied. The selected co-fed olefins include 1-octene, 2-octene and 1-dodecene. Results showed that the addition of ...
متن کاملMechanism of Carbon Monoxide Dissociation on a Cobalt Fischer–Tropsch Catalyst
The way in which the triple bond in CO dissociates, a key reaction step in the Fischer-Tropsch (FT) reaction, is a subject of intense debate. Direct CO dissociation on a Co catalyst was probed by 12C16O/13C18O scrambling in the absence and presence of H2. The initial scrambling rate without H2 was significantly higher than the rate of CO consumption under CO hydrogenation conditions, which indi...
متن کامل281. Promoted Hydrotalcite Based Cobalt Catalyst for Fischer Tropsch Synthesis Application
The effects of using different promoters on hydrotalcite based cobalt (HT-Co) catalyst for FischerTropsch Synthesis was studied in this paper. The HT-Co catalysts were synthesized by using hydrothermal method whereas zinc and zirconium were added separately as promoters, by wetness impregnation method. The main aim of the study is to see the difference in properties of both zinc and zirconium p...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Catalysis Communications
سال: 2020
ISSN: 1566-7367
DOI: 10.1016/j.catcom.2020.106149